I agree with all the others. I've been there several times in mid morning hours; the area around the station does not seem particularly dangerous (there's a Norfork Southern police station near the Amtrak depot, and local police frequent the depot area). But it'd be a hike to get something. If you did want to grab something, I'd be thinking of getting a cab and going someplace, but downtown Toledo is basically dead that time of night. So you'd be headed out a ways to a a suburb. There are vending machines in the station, but you can guess what that means... chips, cookies, and sodas.