As said, no. But some stores (such as Best Buy, Office Depot, Sears, and some others) allow you to buy online, and then pick the items up at the store a few hours later. But to earn AGR points, you must buy the item(s) online, THRU THE POINTS FOR SHOPPING PORTAL!
Even if you order from (say) Best Buy, but enter bestbuy.com directly, you will not earn any AGR points!